[UPSC CSE 2014] Thermodynamics (Q87, 15M)

Consider a system of free gas particles having f degrees of freedom. Use equipartition theorem to establish the relation f=\frac{2}{\left(\dfrac{C_p}{C_V}-1\right)}, where C_p and C_V are molar specific heats at constant pressure and constant volume respectively. Obtain the values of \dfrac{C_p}{C_V} for diatomic and triatomic gases.